7447-41-8 Lithium chloride CAS NO.7447-41-8
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- Min.Order: 1 Metric Ton
- Payment Terms: T/T,
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industrial-grade(1-10)Metric Tonindustrial-grade(10-100)Metric Ton
- Product Details
Keywords
- Lithium chloride
- Lithium chloride
- Lithium chloride
Quick Details
- ProName: 7447-41-8 Lithium chloride
- CasNo: 7447-41-8
- Molecular Formula: ClLi
- Appearance: white flake solid
- Application: battery
- DeliveryTime: one month
- PackAge: 25kg/woven bag
- Port: shanghai
- ProductionCapacity: 10 Metric Ton/Day
- Purity: 99%
- Storage: Keep in dry and cool condition
- Transportation: by sea
- LimitNum: 1 Metric Ton
- Melting point: 605 °C(lit.)
Superiority
Lithium chloride Chemical Properties |
Melting point | 605 °C(lit.) |
Boiling point | 1382°C |
density | 2.06 |
refractive index |
n |
Fp | -4 °F |
storage temp. | 2-8°C |
solubility | H2O: soluble |
form | beads |
color | White to gray |
PH | 5.5-7.5 (25℃, 50mg/mL in H2O) |
Water Solubility | 832 g/L (20 ºC) |
Sensitive | Hygroscopic |
Merck | 14,5528 |
Stability: | Stable. Incompatible with strong oxidizing agents, strong acids, bromine trichloride, bromine trifluoride. Very hygroscopic. Protect from moisture. |
CAS DataBase Reference | 7447-41-8(CAS DataBase Reference) |
NIST Chemistry Reference | Lithium chloride(7447-41-8) |
EPA Substance Registry System | Lithium chloride (LiCl)(7447-41-8) |
Safety Information |
Hazard Codes | F,Xn,C,Xi |
Risk Statements | 11-36/38-22-36/37/38-35-10-36/37-19-63-20/21/22-62-41-40 |
Safety Statements | 26-37/39-36/37/39-16-36-45-33-29-22-36/37 |
RIDADR | UN 2789 8/PG 2 |
WGK Germany | 1 |
RTECS | OJ5950000 |
F | 3-10 |
TSCA | Yes |
HazardClass | 8 |
PackingGroup | III |
HS Code | 28273980 |
Hazardous Substances Data | 7447-41-8(Hazardous Substances Data) |
Toxicity | LD50 in mice (mg/kg): 990 i.p.; in rats (mg/kg): 600 i.p., 4.8 i.v. (Wielosz). |
Lithium chloride Usage And Synthesis |
Chemical Properties |
White cubic crystals; granules or powder; hygroscopic; sharp salt-like taste; refractive index 1.662; density 2.068 g/cm3; melts at 605°C; vaporizes around 1,360°C; readily dissolves in water (64g/100mL at 0°C); also highly soluble in alcohol and pyridine; moderately soluble in acetone (4.1 g/100mL at 25°C). It dehumidifies air for industrial drying and for air conditioning. Lithium chloride bums with a chrims on flame and is used in pyrotechnics. It is also used as a pyrotechnic in welding and brazing fluxes. |
Uses | manufacture of mineral waters; in pyrotechnics; soldering aluminum; in refrigerating machines. |
Definition | ChEBI: A metal chloride salt with a Li(+) counterion. |
Preparation |
Lithium chloride may be prepared by reaction of lithium carbonate or lithium hydroxide with hydrochloric acid followed by crystallization: Li2CO3+ 2HCl →2LiCl + CO2+ H2O LiOH + HCl →LiCl + H2O Crystallization above 95°C yields anhydrous salt. Hot solution upon cooling forms crystals of monohydrate, LiCl.H2O. Lithium chloride can be synthesized from its elements by heating lithium metal with chlorine gas. It also may be obtained from natural brine. |
General Description | Colorless crystals or powder. Low toxicity. |
Air & Water Reactions | Very hygroscopic. Very soluble in water. |
Reactivity Profile | These materials have weak oxidizing or reducing powers. Redox reactions can however still occur. For example, CO2, which is often regarded as chemically inert, vigorously oxidizes the strong reducing agent Mg if the two are heated together. The majority of compounds in this class are slightly soluble or insoluble in water. If soluble in water, then the solutions are usually neither strongly acidic nor strongly basic. These compounds are not water-reactive. Some do react with acids: carbonates generate carbon dioxide and heat when treated with acids; fluorides, sulfites and sulfides generate toxic gases (hydrogen fluoride, sulfur dioxide and hydrogen sulfide, respectively) when treated with acids. |
Fire Hazard | Flash point data for Lithium chloride are not available. Lithium chloride is probably combustible. |
Safety Profile | Human poison by ingestion. Experimental poison by intravenous and intracerebral routes. Moderately toxic by subcutaneous and intraperitoneal routes. Experimental teratogenic and reproductive effects. Human systemic effects by ingestion: somnolence, tremors, nausea or vomiting. An eye and severe skin irritant. Human mutation data reported. Questionable carcinogen with experimental neoplastigenic data. This material has been recommended and used as a substitute for sodwm chloride in "saltfree" diets, but cases have been reported in which the ingestion of lithium chloride has produced dminess, ringing in the ears, visual disturbances, tremors, and mental confusion. In most cases, the symptoms disappeared when use was discontinued. Prolonged absorption may cause disturbed electrolyte balance, impaired renal function. Reaction is violent with BrF3. When heated to decomposition it emits toxic fumes of Cl-. Used for dehumidification in the air conditioning industry. Also used to obtain lithum metal. See also LITHIUM COMPOUNDS. |
Purification Methods | Crystallise it from water (1mL/g) or MeOH and dry it for several hours at 130o. Other metal ions can be removed by preliminary crystallisation from hot aqueous 0.01M disodium EDTA. It has also been crystallised from conc HCl, fused in an atmosphere of dry HCl gas, cooled under dry N2 and pulverised in a dry-box. Kolthoff and Bruckenstein [J Am Chem Soc 74 2529 1952] precipitated it with ammonium carbonate, washed it with Li2CO3 five times by decantation and finally with suction, then dissolved it in HCl. The LiCl solution is evaporated slowly with continuous stirring in a large evaporating dish, the dry powder being stored (while still hot) in a desiccator over CaCl2. |
Lithium chloride Preparation Products And Raw materials |
Details
Coreychem |
Henan CoreyChem Co., Ltd, based on the original Zhengzhou Cote Chemical Research Institute, be brave in absorbing highly educated talents & overseas returnees; actively responded to Zhengzhou City High-tech Zone Government’s Special Care Policy, reorganized and founded in National University of Science and Technology Park, which is a high-tech, stock enterprise of high-end chemical Custom synthesis;The park was created by the People's Government of Henan Province, and proved by Ministry of Education and the National Science & Technology, taking the construction mode of "many college a park, and common development", mainly depends on Zhengzhou University and Henan University’s scientific research and talent advantage to set up Universities, scientific research institute and enterprise scientific research achievements transformation platform, to make high-tech enterprises incubate, is the new high-tech talent gathering base, high and new technology industry enterprise radiation base, colleges and universities technological innovation base.
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