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- Top rated AMBROX DL(3738-00-9)
- Various Specifications AMBROX DL(3738-00-9)
- AMBROX DL(3738-00-9)
Quick Details
- ProName: Supply high quality AMBROX DL(3738-00...
- CasNo: 3738-00-9
- Molecular Formula: C16H28O
- Appearance: ask
- Application: ask
- DeliveryTime: Three days later
- PackAge: customer demand
- Port: Shanghai or Qingdao
- ProductionCapacity: 50 Kilogram/Month
- Purity: 94%~99%
- Storage: ask
- Transportation: by sea or by air
- LimitNum: 1 Gram
- Boiling point: 273.9±8.0 °C(Predicted)
- density: 0.939±0.06 g/cm3(Predicted)
Superiority
Details
Product Name: | AMBROX DL |
Synonyms: | 1-b]furan,dodecahydro-3a,6,6,9a-tetramethyl-Naphtho[2;Dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]furan;AMBROX DL;DODECAHYDRO-3A,6,6,9A-TETRAMETHYLNAPHTO-(2,1-B)-FURAN;Dodecahydro-3a,6,6,9a-tetramethylnaphtho[2,1-b]fur;Ambermor;Tetramethyl perhydronaphthofuran;Naphtho2,1-bfuran, dodecahydro-3a,6,6,9a-tetramethyl- |
CAS: | 3738-00-9 |
MF: | C16H28O |
MW: | 236.39 |
EINECS: | 223-118-6 |
Product Categories: | - |
Mol File: | 3738-00-9.mol |
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AMBROX DL Chemical Properties |
Melting point | 75-76 °C |
Boiling point | 273.9±8.0 °C(Predicted) |
density | 0.939±0.06 g/cm3(Predicted) |
FEMA | 3471 | 1,5,5,9-TETRAMETHYL-13-OXATRICYCLO(8.3.0.0(4,9))TRIDECANE |
JECFA Number | 1240 |
Safety Information |
AMBROX DL Usage And Synthesis |
Chemical Properties | 3a,6,6,9a-Tetramethyldodecahydronaphtho[2,1-b]furan is a crystalline autoxidation product of ambrein with a typical ambergris odor. It is prepared from ( )-sclareol, a diterpene alcohol obtained from extraction of clary sage plants. Oxidative degradation to a lactone (“sclareolide”), hydrogenation of the latter to the corresponding diol, and dehydration yield the title compound. |
Occurrence | Reported found in clary sage oil. |
Preparation | Racemic sclareolide can be prepared by cyclization of homofarnesic acid in the presence of SnCl4 as a catalyst . Pure diastereomers are obtained by acid cyclization of (E)- and (Z)-4-methyl-6-(2,6,6-trimethylcyclohex-l(2)-enyl)-3- hexen-1-ol, prepared from 2-methyl-4-(2,6,6-trimethylcyclohex-l(2)-enyl)-2- butenal [394]. If the racemic sclareolide mixture is resolved into its enantiomers, the (–)-oxide may also be obtained by a totally synthetic route |
Trade name | Compound starting from natural sclareol: Ambermore, Ambermore-DL, Ambermore-EX (Aromor), Ambrox® Super (Firmenich), Ambroxan® (Kao), Ambroxide (Symrise); compound starting from homofarnesic acid derivatives: Ambrox® DL (Firmenich); compound starting from 2-methyl- 4-(2,6,6-trimethylcyclohex-l(2)enyl)-2-butenal: Cetalox® (Firmenich), Cetalor (Aromor). |
AMBROX DL Preparation Products And Raw materials |