Clopyralid CAS NO.1702-17-6

Product Name: Clopyralid

Synonyms: CLOPYRALID;DOWCO 290(R);DICHLOROPYRIDINE ACID;LONCID;LONTREL (TM);CLOPYRALID PESTANAL (3,6-DICHLOROPYRIDIN;LONTREL, 250MG, NEAT;2-Pyridinecarboxylic acid, 3,6-dichloro-

CAS: 1702-17-6

MF: C6H3Cl2NO2

MW: 192

EINECS: 216-935-4

Product Categories: pharmacetical;Organic acids;Agro Products;HERBICIDE;Agro-Products;Heterocycles;Heterocycle-Pyridine series;Alphabetic;Analytical Standards;L

Mol File: 1702-17-6.mol

Clopyralid Structure

Clopyralid Chemical Properties

Melting point 151-152°C

Boiling point 0°C

density 1.4313 (rough estimate)

refractive index 1.6100 (estimate)

Fp 0°C

storage temp. 0-6°C

form neat

Water Solubility 1.0 g/L

Merck 14,2400

BRN 473755

CAS DataBase Reference 1702-17-6(CAS DataBase Reference)

EPA Substance Registry System 2-Pyridinecarboxylic acid, 3,6-dichloro-(1702-17-6)

Safety Information

Hazard Codes Xi;N,Xi,N,X

Risk Statements 41-51/53

Safety Statements 26-30-61-39

RIDADR UN 3077

WGK Germany 3

RTECS TJ7550700

TSCA Yes

HazardClass 9

PackingGroup III

Hazardous Substances Data 1702-17-6(Hazardous Substances Data)

Toxicity LD50 in male, female rats (mg/kg): >5000, 4300 orally; LC50 (96 hr) to rainbow trout: 103.5 mg/l (Brown, Uprichard)

MSDS Information

Clopyralid Usage And Synthesis

Chemical Properties White Crystalline Solid

Chemical Properties Odorless and colorless crystalline solid. Odorless. Available as a soluble concentrate that is usually mixed with water. Combustible

Uses Systemic post-emergence herbicide for use in food crops and mesquite.

Definition ChEBI: An organochlorine pesticide having a 3,6-dichlorinated picolinic acid structure.

Agricultural Uses Herbicide: Clopyralid is used to control annual and perennial broadleaf weeds on rangeland, pastures, turf and lawns, rights-of-way and a few agricultural products such as sugar beets, oats, barley, mint and wheat.

Trade name ACCENT®; CONFRONT®; CURTAIL®; CURTAIL M®; DOWCO®-290; HORNET®; LONTREL®; LONTREL® 3; LONTRIL® F; LONTRIL® T; MATRIGON®; MILLENNIUM®; NAF®-280; PARADIGM®; RECLAIM®; REDEEM®; RIVERDALE®; SCORPION®; STINGER®; TRANSLINE®; WIDEMATCH®; XRM-3972®

Potential Exposure Clopyralid is a pyralid herbicide used to control annual and perennial broadleaf weeds on rangeland, pastures, turf, and lawns, rights-of-way and a few agricultural products such as sugarbeets, oats, barley, mint, and wheat.

Shipping UN3077 Environmentally Hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required

Incompatibilities May react violently with strong oxidizers, bromine, 90% hydrogen peroxide, phosphorus trichloride, silver powders, or dust. Incompatible with silver compounds. Mixture with some silver compounds forms explosive salts of silver oxalate. Keep away from oxidizers, sulfuric acid, caustics, ammonia, aliphatic amines, alkanolamines, isocyanates, alkylene oxides, epichlorohydrin. Solutions are strong acids; corrosive to aluminum, iron, and tin. Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water, and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, sulfides (releasing heat, toxic, and possibly flammable gases), thiosulfates, and dithionites (releasing hydrogen sulfate and oxides of sulfur).

Waste Disposal Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an Clopyralid 877 afterburner and scrubber. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers.

Clopyralid Preparation Products And Raw materials

Raw materials Chlorine

Henan CoreyChem Co., Ltd, based on the original Zhengzhou Cote Chemical Research Institute, be brave in absorbing highly educated talents & overseas returnees; actively responded to Zhengzhou City High-tech Zone Government’s Special Care Policy, reorganized and founded in National University of Science and Technology Park, which is a high-tech, stock enterprise of high-end chemical Custom synthesis;The park was created by the People's Government of Henan Province, and proved by Ministry of Education and the National Science & Technology, taking the construction mode of "many college a park, and common development", mainly depends on Zhengzhou University and Henan University’s scientific research and talent advantage to set up Universities, scientific research institute and enterprise scientific research achievements transformation platform, to make high-tech enterprises incubate,  is the new high-tech talent gathering base, high and new technology industry enterprise radiation base, colleges and universities technological innovation base.

 

Henan Coreychem Co., Ltd, facing global High-tech pharmaceutical raw materials, high complex new type intermediates, fine chemicals custom synthesis, scale-up production and Rare chemicals trade. Corey have well-equipped machine, strong technical force and considerate marketing team service. We also have rich experience advantage in basic research, small scale process development, scale-up, industrial technology development & production and cost control.

 

Our R&D center building area is 811 square meters, with 3 contributing proffesor of technical advisor, 4 Dr., 10 masters, and 28 research staff. Our level of chemical synthesis is known to the industry. So we have accumulated rich experience in synthetic methods design and exploring the synthesis of new technology. Not only we are good in heterocyclic chemistry, chiral chemistry (asymmetric synthesis and enzyme reactions), metal organic synthesis, high throughput chemistry, also specializes in bioorganic chemistry, including nucleosides, nucleotides, sugar chemistry, peptide chemistry. R & D center has many sets of 10 liters, 20 liters, 50 liters, 100L multifunction high and low pressure reaction still, rotary evaporator, anhydrous anaerobic reaction devices, hydrogenation equipment, cryogenic process (-120 degrees) equipment, to complete mg level custom synthesis and kg level process development experiments. The Existing 600M NMR, LCMS, Fourier Infrared Spectrometer, liquid chromatography, differentialscanning calorimetry, and other advanced detection equipment areto ensure quality and efficient completion of R&D projects. So far our completed custom synthesis products is more than 5300 species, where dozens of them are non-CAS declaration products, almost including all types of organic reactions.

 

At present, in addition to our headquarters in Zhengzhou, we also have another product base in Jun County, Henan Province. This base is the attracting investment of science and technology project of Jun County govenment’s, which covers 6529 square meters. In addition to bear our own company’s 1000L-5000L pilot task, also bear the function of Henan pilot incubation service platform, In order to improve Henan and surroundings’ synthetic reaction pilot service ability and the key technology development capabilities. Base with three GMP standards workshop, a testing center, one test center,one experiment center and associatd supporting facilities, can carry out oxidation, hydrogenation (70 kg pressure), halogenated, acieration, etherification, condensation, cyclization, formatting, ammoniated, diazotization andpilot service such as azide reactions etc. In the future we will work hard to make it become the most complete production system in central China and even the whole country, the highest technical level, the strongest talent team, the most popular service scope of pilot incubation service platform.

 

Henan Coreychem co., LTD. is committed to provide cost effective chemical service to the global fine chemical industry product development agencies; we adhering to the consistent good commercial reputation, to create a highly efficient, high quality of chemical research, development, production, sales and service of integrated platform, let our customers faster, better get ideal and thoughtful service.