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Home > Products >  reliable quality Bis(methylthio)methane

reliable quality Bis(methylthio)methane CAS NO.1618-26-4

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  • ProName: reliable quality Bis(methylthio)meth...
  • CasNo: 1618-26-4
  • Molecular Formula: C3H8S2
  • Appearance: according to email quotation
  • Application: pharmaceutical raw materials
  • DeliveryTime: Within 3 days after payment
  • PackAge: foil aluminium bag/vacuum packing
  • Port: Shanghai
  • ProductionCapacity: 100 Kilogram/Week
  • Purity: 99%
  • Storage: Keep in dry and cool condition
  • Transportation: by air or by sea
  • LimitNum: 1 Kilogram
  • CAS No.: 1618-26-4
  • Synonyms: 2,4-DITHIAPENTANE
  • Formula: C3H8S2
  • Molecular Weight: 108.23

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Details

Product Name: Bis(methylthio)methane
Synonyms: 2,4-DITHIAPENTANE;FEMA 3878;FORMALDEHYDE DIMETHYL MERCAPTAL;DIMETHYLTHIOMETHANE;BIS(METHYLMERCAPTO)METHANE;BIS(METHYLTHIO)METHANE;METHYLENEBIS(METHYL SULFIDE);Bis(methylsulfanyl)methane
CAS: 1618-26-4
MF: C3H8S2
MW: 108.23
EINECS: 216-577-9
Product Categories: -;Industrial/Fine Chemicals;sulfide Flavor;Building Blocks;Chemical Synthesis;Organic Building Blocks;Sulfides/Disulfides;Sulfur Compounds
Mol File: 1618-26-4.mol
Bis(methylthio)methane Structure
 
Bis(methylthio)methane Chemical Properties
Melting point  148 °C
Boiling point  147 °C(lit.)
density  1.059 g/mL at 25 °C(lit.)
refractive index  n20/D 1.53(lit.)
FEMA  3878 | BIS-(METHYLTHIO)METHANE
Fp  111 °F
storage temp.  Flammables area
solubility  IMMISCIBLE
form  neat
Specific Gravity 1.059
color  APHA: ≤100
Water Solubility  IMMISCIBLE
Merck  14,1256
JECFA Number 533
BRN  1731143
CAS DataBase Reference 1618-26-4(CAS DataBase Reference)
NIST Chemistry Reference 2,4-Dithiapentane(1618-26-4)
EPA Substance Registry System Methane, bis(methylthio)-(1618-26-4)
 
Safety Information
Hazard Codes  Xi
Risk Statements  10-36/37/38
Safety Statements  16-26-36/37/39
RIDADR  UN 1993 3/PG 3
WGK Germany  3
13
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29309070
MSDS Information
Provider Language
2,4-Dithiapentane English
SigmaAldrich English
ACROS English
ALFA English
 
Bis(methylthio)methane Usage And Synthesis
Chemical Properties CLEAR COLOURLESS TO PALE YELLOW LIQUID
Chemical Properties bis-(Methylthio)methane has a mustard-like odor.
Occurrence Reported found in Camembert and Gruyere cheeses, milk, fish oil, cooked and canned beef, shitake mushroom, truffle, prawn and lobster.
Purification Methods Work in an efficient fume cupboard as the substance may contain traces (or more) of methylmercaptan which has a very bad odour. Dissolve the mercaptal in Et2O, shake it with aqueous alkalis then dry it over anhydrous K2CO3, filter and distil it over K2CO3 under a stream of N2. If the odour is very strong, then allow all gas efluents to bubble through 5% aqueous NaOH solution which is then treated with dilute KMnO4 in order to oxidise MeSH to odourless products. UV: max 238 nm (log 2.73) [Fehnel & Carmack J Am Chem Soc 71 90 1949, Fehér & Vogelbruch Chem Ber 91 996 1958, B.hme & Marz Chem Ber 74 1672 1941]. Oxidation with aqueous KMnO4 yields bis-(methylsulfonyl)methane which has m 142-143o [Fiecchi et al. Tetrahedron Lett 1681 1967]. [Beilstein 1 IV 3088.]
 
Bis(methylthio)methane Preparation Products And Raw materials
Preparation Products Methyl 2-(methylamino)benzoate

 

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