Triclopyr /high quality CAS NO.55335-06-3

Product Name: Triclopyr

Synonyms: CrossbowTurflon;Curtail;Dowco 233;dowco233;Exetor;Garlon;grazonet;Mutan

CAS: 55335-06-3

MF: C7H4Cl3NO3

MW: 256.47

EINECS: 259-597-3

Product Categories: -;Agro-Products;Aromatics;Heterocycles;HERBICIDE;Alpha sort;Herbicides;Pesticides&Metabolites;PyridinePesticides&Metabolites;Q-ZAlphabetic;TP - TZ;PyridineAlphabetic

Mol File: 55335-06-3.mol

Triclopyr Structure

Triclopyr Chemical Properties

Melting point 148-150°C

Boiling point 290°C

density 1.7626 (rough estimate)

refractive index 1.6200 (estimate)

storage temp. 0-6°C

form Liquid

pka 2.68(at 25℃)

Merck 13,9730

BRN 225301

CAS DataBase Reference 55335-06-3(CAS DataBase Reference)

NIST Chemistry Reference Acetic acid, [(3,5,6-trichloro-2-pyridinyl)oxy]-(55335-06-3)

EPA Substance Registry System Acetic acid, [(3,5,6-trichloro-2-pyridinyl) oxy]-(55335-06-3)

Safety Information

Hazard Codes Xn

Risk Statements 22

Safety Statements 22-24/25

RIDADR UN3082 (liquid)

WGK Germany 3

RTECS AJ9000000

Hazardous Substances Data 55335-06-3(Hazardous Substances Data)

Toxicity LD50 orally in rats: 713 mg/kg (Kenaga)

MSDS Information

Triclopyr Usage And Synthesis

Chemical Properties White to Off-White Solid

Uses Selective postemergence herbicide to control many woody and broad-leaved weeds.

Uses Triclopyr is a selective post-emergence herbicide.

Definition ChEBI: A monocarboxylic acid that is (pyridin-2-yloxy)acetic acid substituted by chloro groups at positions 3, 5 and 6. It is an agrochemical used as a herbicide.

Agricultural Uses Herbicide: Triclopry is a systemic herbicide used on rice, range land and pasture, rights-of-way, forestry and grasslands, including home lawns, for control of broadleaf weeds and woody plants. Triclopry is usually available as a triclopyr butoxyethyl ester (BEE) or as a triclopry triethylamine salt (TEA). Registered for use in the U.S. Some products may be classified as Restricted Use Pesticides (RUP). Registered for use in EU countries . U.S. Maximum Allowable Residue Levels for Triclopyr and its metabolites 3,5,6,-trichloro-2-pyridinol and 2-methoxy-3,5,6-trichloropyridine [40 CFR 180.417 (a)(1)]: for the combined residues of the herbicide in or on the following raw agricultural commodities: fish 3.0 ppm; grass, forage 500 ppm; grass, forage, hay 500 ppm;shellfish3.5 ppm.[40 CFR 180.417 (a)(2)]: in or on the following agricultural commodities: egg 0.05 ppm; meat, fat, and meat byproducts, except kidney and liver, of cattle, goat, hog, horse and sheep 0.05 ppm; meat, fat, and meat byproducts, except kidney, of poultry 0.1 ppm; milk 0.01 ppm; liver and kidney of cattle, goat, hog, horse and sheep 0.5 ppm; rice, grain 0.3 ppm; rice, straw10.0 ppm.

Trade name [Note: See the following record, Triclopyr, triethylamine salt, for trade names containing the salt of triclopry] ACCESS®; CROSSBOW®, (triclopyr + 2,4-D ester); ET®; GARLON®; GRAZON® Triclopyr; PATHFINDER®; REDEEM®; RELY®; REMEDY®; RIVERDALE TAHOE® Nufarm (Australia); TURFLON®

Environmental Fate Soil. In soil, triclopyr degraded to 3,5,6-trichloro-2-pyridinol and 2-methoxy-3,5,6- trichloropyridine (Norris et al., 1987). The major route of dissipation from soil is likely due to microbial degradation (Newton et al., 1990).

Fifty-four days after triclopyr was applied to soil at a rate of 5.6 kg/ha, the majority (65%) remained in the top 10 cm of soil (Lee et al., 1986a).

Ashton and Monaco (1991) reported triclopyr had an average half-life of 46 days and is in uenced by soil type and climatic conditions.

Plant. Lewer and Owen (1989) found 3,5,6-trichloro-2-pyridinol as the major metab- olite in plants. Cultured soybean cells metabolized triclopyr to dimethyl triclopyr-aspartate and dimethyl triclopyr-glutamate which can be rehydrolyzed to form the parent compound.

At an application rate of 3.4 kg/ha, the dissipation half-life was 3.7 days. At an application rate of 3.3 kg/ka, the dissipation half-lives of triclopyr in brown, browse and litter samples were 73.5, 202.3 and 31 days, respectively (Norris et al., 1987).

Metabolic pathway After 7 days in a soybean cell suspension culture, the major metabolites of trichlopyr are formed and identified as the aspartate (major) and glutamate (minor) amide conjugates.

Triclopyr Preparation Products And Raw materials

Raw materials 2,3,5,6-Tetrachloropyridine

Henan CoreyChem Co., Ltd, based on the original Zhengzhou Cote Chemical Research Institute, be brave in absorbing highly educated talents & overseas returnees; actively responded to Zhengzhou City High-tech Zone Government’s Special Care Policy, reorganized and founded in National University of Science and Technology Park, which is a high-tech, stock enterprise of high-end chemical Custom synthesis;The park was created by the People's Government of Henan Province, and proved by Ministry of Education and the National Science & Technology, taking the construction mode of "many college a park, and common development", mainly depends on Zhengzhou University and Henan University’s scientific research and talent advantage to set up Universities, scientific research institute and enterprise scientific research achievements transformation platform, to make high-tech enterprises incubate,  is the new high-tech talent gathering base, high and new technology industry enterprise radiation base, colleges and universities technological innovation base.

 

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