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Diphenylmethane competitive product CAS NO.101-81-5
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Quick Details
- ProName: Diphenylmethane competitive product
- CasNo: 101-81-5
- Molecular Formula: C13H12
- Appearance: according to email quotation
- Application: pharmaceutical raw materials
- DeliveryTime: Within 3 days after payment
- PackAge: foil aluminium bag/vacuum packing
- Port: Shanghai
- ProductionCapacity: 100 Kilogram/Week
- Purity: 99%
- Storage: Keep in dry and cool condition
- Transportation: by air or by sea
- LimitNum: 1 Kilogram
- CAS No.: 101-81-5
- Synonyms: Benzene,1,1’-methylenebis-
- Formula: C13H12
- Molecular Weight: 168.23
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Details
| Product Name: | Diphenylmethane |
| Synonyms: | Benzene,1,1’-methylenebis-;diphenyl-methan;Ditan;Methane, diphenyl-;ai3-28021-x;Artificialgeranium;Cefixime O,O';Benaylbenzene |
| CAS: | 101-81-5 |
| MF: | C13H12 |
| MW: | 168.23 |
| EINECS: | 202-978-6 |
| Product Categories: | Pharmaceutical Intermediates;- |
| Mol File: | 101-81-5.mol |
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| Diphenylmethane Chemical Properties |
| Melting point | 24.5 °C |
| Boiling point | 265 °C |
| density | 1.006 g/mL at 25 °C(lit.) |
| vapor density | 5.79 (vs air) |
| vapor pressure | <1 mm Hg ( 77 °C) |
| refractive index |
n |
| Fp | >230 °F |
| storage temp. | Store below +30°C. |
| solubility | Soluble in ethanol, ether, benzene and chloroform. |
| pka | 33.5(at 25℃) |
| form | Low Melting Solid |
| Specific Gravity | 1.006 |
| color | Colorless to pale yellow |
| explosive limit | 0.69-8.66%(V) |
| Merck | 14,3328 |
| BRN | 1904982 |
| CAS DataBase Reference | 101-81-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Diphenylmethane(101-81-5) |
| EPA Substance Registry System | Benzene, 1,1'-methylenebis-(101-81-5) |
| Safety Information |
| Hazard Codes | Xn |
| Risk Statements | 22 |
| Safety Statements | 24/25-58-54-44-29 |
| RIDADR | UN3077 |
| WGK Germany | 2 |
| RTECS | DA4976500 |
| Autoignition Temperature | 905 °F |
| TSCA | Yes |
| HazardClass | 9 |
| PackingGroup | III |
| HS Code | 29029090 |
| Hazardous Substances Data | 101-81-5(Hazardous Substances Data) |
| Toxicity | LD50 orally in Rabbit: 2250 mg/kg LD50 dermal Rabbit > 5000 mg/kg |
| MSDS Information |
| Provider | Language |
|---|---|
| ACROS | English |
| SigmaAldrich | English |
| ALFA | English |
| Diphenylmethane Usage And Synthesis |
| Chemical Properties | Colorless to pale yellow low melting solid |
| Definition | ChEBI: A diarylmethane that is methane substituted by two phenyl groups. |
| Purification Methods | Sublime it under vacuum, or distil it at 72-75o/0.4mm. Recrystallise it from cold EtOH. It has also been purified by fractional crystallisation from the melt. [Armarego Aust J Chem 13 95 1960, Beilstein 5 II 498, 5 IV 1841.] |
| Diphenylmethane Preparation Products And Raw materials |
| Raw materials | Aluminium chloride-->Zinc chloride-->amalgam |
| Preparation Products | Estradiol-->2-(4-CHLOROPHENYL)-3-METHYLBUTYRONITRILE-->α-phenyl-2-p-tolylethylamine-->Azelastine-->Bromodiphenylmethane-->BLASTICIDIN S-->Polymethylene polyphenyl polyisocyanate |
| Product Name: | Diphenylmethane |
| Synonyms: | Benzene,1,1’-methylenebis-;diphenyl-methan;Ditan;Methane, diphenyl-;ai3-28021-x;Artificialgeranium;Cefixime O,O';Benaylbenzene |
| CAS: | 101-81-5 |
| MF: | C13H12 |
| MW: | 168.23 |
| EINECS: | 202-978-6 |
| Product Categories: | Pharmaceutical Intermediates;- |
| Mol File: | 101-81-5.mol |
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|
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| Diphenylmethane Chemical Properties |
| Melting point | 24.5 °C |
| Boiling point | 265 °C |
| density | 1.006 g/mL at 25 °C(lit.) |
| vapor density | 5.79 (vs air) |
| vapor pressure | <1 mm Hg ( 77 °C) |
| refractive index |
n |
| Fp | >230 °F |
| storage temp. | Store below +30°C. |
| solubility | Soluble in ethanol, ether, benzene and chloroform. |
| pka | 33.5(at 25℃) |
| form | Low Melting Solid |
| Specific Gravity | 1.006 |
| color | Colorless to pale yellow |
| explosive limit | 0.69-8.66%(V) |
| Merck | 14,3328 |
| BRN | 1904982 |
| CAS DataBase Reference | 101-81-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Diphenylmethane(101-81-5) |
| EPA Substance Registry System | Benzene, 1,1'-methylenebis-(101-81-5) |
| Safety Information |
| Hazard Codes | Xn |
| Risk Statements | 22 |
| Safety Statements | 24/25-58-54-44-29 |
| RIDADR | UN3077 |
| WGK Germany | 2 |
| RTECS | DA4976500 |
| Autoignition Temperature | 905 °F |
| TSCA | Yes |
| HazardClass | 9 |
| PackingGroup | III |
| HS Code | 29029090 |
| Hazardous Substances Data | 101-81-5(Hazardous Substances Data) |
| Toxicity | LD50 orally in Rabbit: 2250 mg/kg LD50 dermal Rabbit > 5000 mg/kg |
| MSDS Information |
| Provider | Language |
|---|---|
| ACROS | English |
| SigmaAldrich | English |
| ALFA | English |
| Diphenylmethane Usage And Synthesis |
| Chemical Properties | Colorless to pale yellow low melting solid |
| Definition | ChEBI: A diarylmethane that is methane substituted by two phenyl groups. |
| Purification Methods | Sublime it under vacuum, or distil it at 72-75o/0.4mm. Recrystallise it from cold EtOH. It has also been purified by fractional crystallisation from the melt. [Armarego Aust J Chem 13 95 1960, Beilstein 5 II 498, 5 IV 1841.] |
| Diphenylmethane Preparation Products And Raw materials |
| Raw materials | Aluminium chloride-->Zinc chloride-->amalgam |
| Preparation Products | Estradiol-->2-(4-CHLOROPHENYL)-3-METHYLBUTYRONITRILE-->α-phenyl-2-p-tolylethylamine-->Azelastine-->Bromodiphenylmethane-->BLASTICIDIN S-->Polymethylene polyphenyl polyisocyanate |
| Methyl phenylacetate Chemical Properties |
| Boiling point | 218 °C(lit.) |
| density | 1.066 g/mL at 20 °C(lit.) |
| refractive index |
n |
| FEMA | 2733 | METHYL PHENYLACETATE |
| Fp | 195 °F |
| storage temp. | Store below +30°C. |
| form | neat |
| Water Solubility | Miscible with water. |
| Merck | 14,7268 |
| JECFA Number | 1008 |
| BRN | 878795 |
| Stability: | Stable. Combustible. Incompatible with strong oxidizing agents, strong bases. |
| InChIKey | CRZQGDNQQAALAY-UHFFFAOYSA-N |
| CAS DataBase Reference | 101-41-7(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzeneacetic acid, methyl ester(101-41-7) |
| Safety Information |
| Hazard Codes | Xn |
| Risk Statements | 21-R21 |
| Safety Statements | 23-24/25 |
| WGK Germany | 2 |
| RTECS | AJ3175000 |
| TSCA | Yes |
| HS Code | 29163500 |
| MSDS Information |
| Provider | Language |
|---|---|
| Methyl phenylacetate | English |
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| Methyl phenylacetate Usage And Synthesis |
| Description | Methyl phenylacetate belongs to an ester compound form between the methanol and phenylacetate. It chemical formula is C6H5CH2COOCH3. It is generally found in brandy, capsicum, honey, pepper, some wine, coca and coca products. It is mainly used as a flavouring agent, and is also supplemented into perfumes to enhance honey scents. It is also applied for the partition coefficient measurement experiments. It can also be used as the precursor for the manufacture of synthetic perfumes. In addition, as an acylating agent, it can participate in the enantioselective acylation reaction of beta-lactam intermediate catalyzed by the penicillin G amidase. |
| References |
# # # |
| Description |
Methyl phenyl acetate is an organic compound that is the ester formed from methanol and phenyl acetic acid, with the structural formula C6H5CH2COOCH3. It is a clear colorless liquid that is only slightly soluble in water, but very soluble in most organic solvents. Methyl phenyl acetate has a strong odor similar to honey. The odor is so strong that recommended smelling is of a solution with 10% or less methyl phenyl acetate. This compound also naturally occurs in brandy, capsicum, coffee, honey, pepper and some wine. Methyl phenyl acetate is used in the flavor industry and in perfumes to impart honey scents. |
| Chemical Properties | Methyl phenylacetate has an intense odor suggestive of honey and jasmine with a sweet, honey-like flavor. May be prepared by methanolic esterification of the corresponding acid or nitrile; by reacting HCL over a solution of benzyl nitrile in methanol. |
| Chemical Properties | Methyl phenylacetate has an intense odor suggestive of honey and jasmine. It has a sweet, honey-like flavor. |
| Chemical Properties | colourless liquid |
| Occurrence | Reported found in cocoa, coffee, strawberry, pineapple, pepper, hop oil, cognac, peanut, honey, starfruit, Bourbon vanilla, mountain papaya, roasted chicory root and rooibus tea (Aspalathus linearis). |
| Uses | Perfumery, flavors for tobacco, flavoring. |
| Preparation | By methanolic esterification of the corresponding acid or nitrile; by reacting HCl over a solution of benzyl nitrile in methanol |
| Aroma threshold values | Detection: 25 ppb |
| Taste threshold values | Taste characteristics at 30 ppm: floral, fruity, honey, spice, waxy and sweet |
| Safety Profile | Moderately toxic by ingestion and skin contact. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS. |
| Methyl phenylacetate Preparation Products And Raw materials |
| Methyl phenylacetate | |
| Synonyms: | METHYL ALPHA-TOLUATE;METHYL BENZYLFORMATE;METHYL A-TOLUATE;METHYL PHENYLACETATE;FEMA 2733;PHENYLACETIC ACID METHYL ESTER;Methyl phenylacetate/Phenylacetic acid methyl ester;Phenylacetic Acid Phenylacetate |
| CAS: | 101-41-7 |
| MF: | C9H10O2 |
| MW: | 150.17 |
| EINECS: | 202-940-9 |
| Product Categories: | Organics;API intermediates;Alphabetical Listings;Flavors and Fragrances;M-N;C8 to C9;-;Carbonyl Compounds;Esters;flavoring;Pharmaceutical Intermediates |
| Mol File: | 101-41-7.mol |
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| Methyl phenylacetate Chemical Properties |
| Boiling point | 218 °C(lit.) |
| density | 1.066 g/mL at 20 °C(lit.) |
| refractive index |
n |
| FEMA | 2733 | METHYL PHENYLACETATE |
| Fp | 195 °F |
| storage temp. | Store below +30°C. |
| form | neat |
| Water Solubility | Miscible with water. |
| Merck | 14,7268 |
| JECFA Number | 1008 |
| BRN | 878795 |
| Stability: | Stable. Combustible. Incompatible with strong oxidizing agents, strong bases. |
| InChIKey | CRZQGDNQQAALAY-UHFFFAOYSA-N |
| CAS DataBase Reference | 101-41-7(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzeneacetic acid, methyl ester(101-41-7) |
| Safety Information |
| Hazard Codes | Xn |
| Risk Statements | 21-R21 |
| Safety Statements | 23-24/25 |
| WGK Germany | 2 |
| RTECS | AJ3175000 |
| TSCA | Yes |
| HS Code | 29163500 |
| MSDS Information |
| Provider | Language |
|---|---|
| Methyl phenylacetate | English |
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| Methyl phenylacetate Usage And Synthesis |
| Description | Methyl phenylacetate belongs to an ester compound form between the methanol and phenylacetate. It chemical formula is C6H5CH2COOCH3. It is generally found in brandy, capsicum, honey, pepper, some wine, coca and coca products. It is mainly used as a flavouring agent, and is also supplemented into perfumes to enhance honey scents. It is also applied for the partition coefficient measurement experiments. It can also be used as the precursor for the manufacture of synthetic perfumes. In addition, as an acylating agent, it can participate in the enantioselective acylation reaction of beta-lactam intermediate catalyzed by the penicillin G amidase. |
| References |
# # # |
| Description |
Methyl phenyl acetate is an organic compound that is the ester formed from methanol and phenyl acetic acid, with the structural formula C6H5CH2COOCH3. It is a clear colorless liquid that is only slightly soluble in water, but very soluble in most organic solvents. Methyl phenyl acetate has a strong odor similar to honey. The odor is so strong that recommended smelling is of a solution with 10% or less methyl phenyl acetate. This compound also naturally occurs in brandy, capsicum, coffee, honey, pepper and some wine. Methyl phenyl acetate is used in the flavor industry and in perfumes to impart honey scents. |
| Chemical Properties | Methyl phenylacetate has an intense odor suggestive of honey and jasmine with a sweet, honey-like flavor. May be prepared by methanolic esterification of the corresponding acid or nitrile; by reacting HCL over a solution of benzyl nitrile in methanol. |
| Chemical Properties | Methyl phenylacetate has an intense odor suggestive of honey and jasmine. It has a sweet, honey-like flavor. |
| Chemical Properties | colourless liquid |
| Occurrence | Reported found in cocoa, coffee, strawberry, pineapple, pepper, hop oil, cognac, peanut, honey, starfruit, Bourbon vanilla, mountain papaya, roasted chicory root and rooibus tea (Aspalathus linearis). |
| Uses | Perfumery, flavors for tobacco, flavoring. |
| Preparation | By methanolic esterification of the corresponding acid or nitrile; by reacting HCl over a solution of benzyl nitrile in methanol |
| Aroma threshold values | Detection: 25 ppb |
| Taste threshold values | Taste characteristics at 30 ppm: floral, fruity, honey, spice, waxy and sweet |
| Safety Profile | Moderately toxic by ingestion and skin contact. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS. |
| Methyl phenylacetate Preparation Products And Raw materials |